产品说明
应用
DuPhos and BPE Ligands: Highly Efficient Privileged Ligands
Catalyst for:
- Preparation of a key unit B precursor of cryptophycins via Horner-Wadsworth-Emmons reaction and asymmetric hydrogenation
- Preparation of constrained phenylalanine analogs via Heck reaction followed by asymmetric hydrogenation and cyclization steps
- Enantioselective preparation of N-benzyloxy-β-amino acid Me esters by hydrogenation of α-(benzyloxyaminomethyl)acrylate stereoisomers
- Preparation of fluoro amino acids as synthons for potent macrocyclic HCV NS3 protease inhibitors
- Stereoselective preparation of triply isotope-labeled Ser, Cys, and Ala
- Preparation of β-amino acids from asymmetric hydrogenation of α-(aminomethyl)acrylates
- Asymmetric hydrogenation of a-primary and secondary amino ketones and asymmetric synthesis of (-)-arbutamine and (-)-denopamine
包装
50, 250 mg in amber glass bottle
法律信息
与 Kanata Chemical Technologies Inc. 联合销售,仅供研究使用。这些化合物由 E.I. du Pont de Nemours and Company 授权制造和销售,此许可不包括利用这些化合物制备在制药领域销售的产品的权利。
基本信息
经验(实验)分子式 | C30H48BF4P2Rh |
分子量 | 660.36 |
PubChem化学物质编号 | 329761249 |
NACRES | NA.22 |
产品性质
形式 | powder |
SMILES string | [Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.CC[C@H]2CC[C@H](CC)P2c3ccccc3P4[C@@H](CC)CC[C@@H]4CC |
InChI | 1S/C22H36P2.C8H12.BF4.Rh/c1-5-17-13-14-18(6-2)23(17)21-11-9-10-12-22(21)24-19(7-3)15-16-20(24)8-4;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h9-12,17-20H,5-8,13-16H2,1-4H3;1-2,7-8H,3-6H2;;/q;;-1;+1/b;2-1-,8-7-;;/t17-,18-,19-,20-;;;/m0.../s1 |
InChI key | DSYBEQKPSKLNMC-ZCTOJWETSA-N |
安全信息
储存分类代码 | 11 - Combustible Solids |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |
个人防护装备 | Eyeshields, Gloves, type N95 (US) |