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(S)-Ru(OAc)2(SEGPHOS®)

Diacetato[(S)-(-)-5,5′-bis(diphenylphosphino)-4,4′-bi-1,3-benzodioxole]ruthenium(II)

品牌
Sigma-Aldrich
CAS
373650-12-5
货号
693243
包装型号
规格纯度
参考价格
351.58 *本价格含增值税费
促销
数量
-+
产品介绍:

产品说明

应用

(S)-Ru(OAc)2(SEGPHOS®) can be used as a catalyst:

  • To prepare highly chemo, enantio, and diastereoselective primary β-amino lactams by asymmetric reductive amination of racemic β-keto lactams.
  • To synthesize chiral primary diarylmethylamines and sterically bulky benzylamines from diaryl and sterically hindered ketones via asymmetric reductive amination reaction.
  • For the conversion of levulinic acid to optically active γ-valerolactone via asymmetric hydrogenation reaction.


Takasago Ligands and Complexes for Asymmetric Reactions

包装

50, 100 mg in amber glass bottle

法律信息

与 Takasago 合作销售,仅用于研究目的。日本注册号 3148136
SEGPHOS is a registered trademark of Takasago Intl. Corp.

基本信息

经验(实验)分子式C42H34O8P2Ru
分子量829.73
MDL编号MFCD09753024
PubChem化学物质编号329761576
NACRESNA.22

产品性质

形式powder
储存温度2-8℃
InChI1S/C38H28O4P2.2C2H4O2.Ru/c1-5-13-27(14-6-1)43(28-15-7-2-8-16-28)33-23-21-31-37(41-25-39-31)35(33)36-34(24-22-32-38(36)42-26-40-32)44(29-17-9-3-10-18-29)30-19-11-4-12-20-30;2*1-2(3)4;/h1-24H,25-26H2;2*1H3,(H,3,4);/q;;;+2/p-2
InChI keyBHGLLIGZFQVMBJ-UHFFFAOYSA-L

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable

Sigma-Aldrich

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