产品介绍：
产品说明
应用
(S)-P-Phos can be used as a ligand:
- In the asymmetic hydrogenation reactions.
- For the preparation of chiral ketone functionalized polymers by copolymerization reaction.
- To synthesize chiral alkynes by asymmetric hydroalkynylation of nonpolar alkenes or norbornadienes using iridium catalyst.
- In the selective allylic alkylation of indoles using palladium catalyst.
Ligand employed in the asymmetic hydrogenation of ß-keto esters, 2-arylacrylates, aryl ketones , and other substrates.
包装
100 mg in clear glass bottle
500 mg in amber glass bottle
法律信息
与 Johnson Matthey Catalyst 联合销售，仅供研究使用。适用美国专利 US5886182 以及由此产生的任何专利。
基本信息
| 经验(实验)分子式 | C38H34N2O4P2 |
| 分子量 | 644.64 |
| MDL编号 | MFCD04038734 |
| PubChem化学物质编号 | 24885300 |
| NACRES | NA.22 |
产品性质
| 测定 | 97% |
| 旋光性 | [α]20/D -98°, c = 1 in chloroform |
| mp | 261-265 ℃ |
| SMILES string | COc1cc(P(c2ccccc2)c3ccccc3)c(c(OC)n1)-c4c(OC)nc(OC)cc4P(c5ccccc5)c6ccccc6 |
| InChI | 1S/C38H34N2O4P2/c1-41-33-25-31(45(27-17-9-5-10-18-27)28-19-11-6-12-20-28)35(37(39-33)43-3)36-32(26-34(42-2)40-38(36)44-4)46(29-21-13-7-14-22-29)30-23-15-8-16-24-30/h5-26H,1-4H3 |
| InChI key | JZOSBBLJKXSBBN-UHFFFAOYSA-N |
安全信息
| 储存分类代码 | 13 - Non Combustible Solids |
| WGK | WGK 3 |
| 闪点(F) | Not applicable |
| 闪点(C) | Not applicable |
| 个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
