产品介绍：
产品说明
一般描述
(S)-QUINAP is a bidentate ligand used in catalytic asymmetric hydroboration, hydrogenation, oxidation, and allylic alkylation reactions.
应用
(S)-QUINAP can be used as a ligand:
- In the asymmetric hydrosilylation of alkyl and α, β-unsaturated ketones in the presence of Fe(OAc)2.
- For the synthesis of chiral organoboron compounds by copper-catalyzed β-borylation of α,β-unsaturated esters.
[Ir(cod)Cl]2 treated with ligand (S)-QUINAP forms an iridium complex. This complex is used as a catalyst for the enantioselective hydrogenation of olefins. (S)-QUINAP–Rh complex can be employed as a catalyst in enantioselective hydroboration/oxidation of perfluoroalkenes.
基本信息
| 经验(实验)分子式 | C31H22NP |
| 分子量 | 439.49 |
| Beilstein | 6664856 |
| MDL编号 | MFCD01073773 |
| PubChem化学物质编号 | 329765641 |
| NACRES | NA.22 |
产品性质
| 测定 | ≥95.0% (qNMR) |
| 光学纯度 | enantiomeric excess: ≥98.0% |
| 储存温度 | 2-8℃ |
| InChI | 1S/C31H22NP/c1-3-13-25(14-4-1)33(26-15-5-2-6-16-26)29-20-19-23-11-7-9-17-27(23)30(29)31-28-18-10-8-12-24(28)21-22-32-31/h1-22H |
| InChI key | YMJAIEYASUCCMJ-UHFFFAOYSA-N |
安全信息
| 象形图 |  |
| 警示用语： | Warning-Warning |
| 危险声明 | H302 - H315 - H319 - H335 - H302 - H315 - H319 - H335 |
| 预防措施声明 | P261 - P264 - P270 - P301 + P312 - P302 + P352 - P305 + P351 + P338 - P301 + P312 + P330 - P302 + P352 - P305 + P351 + P338 |
| 危险分类 | Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
| 靶器官 | Respiratory system |
| 储存分类代码 | 11 - Combustible Solids |
| WGK | WGK 3 |
| 闪点(F) | Not applicable |
| 闪点(C) | Not applicable |
