产品介绍：
产品说明
应用
已证实 VANOL 是用于催化型不对称 Diels-Alder 反应、亚胺羟醛反应以及氮杂环丙化反应的绝佳配体。
(R)-VANOL is a vaulted biaryl ligand that may be used in the following processes:
- Transformation of 3-substituted cyclobutanones to enantiopure γ-butyrolactones via asymmetric Baeyer-Villiger Reaction in the presence of an aluminum catalyst.
- Asymmetric aziridination of N-(4-(Methylsulfonyl)benzylidene)diphenylmethanamine to form (2S,3S)-ethyl 1-benzhydryl-3-(4-(methylsulfonyl)phenyl) aziridine-2-carboxylate.
- Conjugate addition of terminal alkynes to 2-arylidene-1,3-diketones with high enantioselectivity in the presence of diethyl zinc.
包装
250 mg in amber glass bottle
基本信息
| 经验(实验)分子式 | C32H22O2 |
| 分子量 | 438.52 |
| MDL编号 | MFCD08459338 |
| PubChem化学物质编号 | 24885264 |
| NACRES | NA.22 |
产品性质
| 测定 | 97% |
| 旋光性 | [α]20/D +310°, c = 1 in chloroform |
| mp | 200-204 ℃ |
| SMILES string | Oc1c(c(cc2ccccc12)-c3ccccc3)-c4c(O)c5ccccc5cc4-c6ccccc6 |
| InChI | 1S/C32H22O2/c33-31-25-17-9-7-15-23(25)19-27(21-11-3-1-4-12-21)29(31)30-28(22-13-5-2-6-14-22)20-24-16-8-10-18-26(24)32(30)34/h1-20,33-34H |
| InChI key | NDTDVKKGYBULHF-UHFFFAOYSA-N |
安全信息
| 象形图 |   |
| 警示用语： | Danger |
| 危险声明 | H315 - H318 - H335 - H413 |
| 预防措施声明 | P273 - P280 - P302 + P352 - P305 + P351 + P338 + P310 |
| 危险分类 | Aquatic Chronic 4 - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3 |
| 靶器官 | Respiratory system |
| 储存分类代码 | 11 - Combustible Solids |
| WGK | WGK 3 |
| 闪点(F) | Not applicable |
| 闪点(C) | Not applicable |
| 个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
