产品介绍：
产品说明
应用
(4R,4′R,5S,5′S)-2,2′-(1-Methylethylidene) or (4S,5R)-Bis-Phbox) can be used as a ligand:
- To prepare selective exo-catalysts for enantioselective 1,3-dipolar cycloaddition reactions.
- In the asymmetric aminooxygenation of alkenes in the presence of tetramethylaminopyridyl radical (TEMPO) as an oxidant and copper(II) triflate as a catalyst.
- In asymmetric aminofluorination of olefins using an iron catalyst.
This chiral Box ligand was most recently shown to mediate an asymmetric aminofluorination of olefins utlizing Xtalfuor-E (719439) and TREAT-HF (344648). The resulting cyclic carbamates can be readily converted into their concomitant beta-fluoro amino acids.
包装
250 mg in amber glass bottle
其他说明
Iron(II)-Catalyzed Intramolecular Olefin Aminofluorination
基本信息
| 经验(实验)分子式 | C33H30N2O2 |
| 分子量 | 486.60 |
| MDL编号 | MFCD24849939 |
| PubChem化学物质编号 | 329768502 |
| NACRES | NA.22 |
产品性质
| 质量水平 | 100 |
| 测定 | 95% |
| mp | 164-169 ℃ |
| SMILES string | CC(C1=N[C@H](C2=CC=CC=C2)[C@H](C3=CC=CC=C3)O1)(C)C4=N[C@H](C5=CC=CC=C5)[C@H](C6=CC=CC=C6)O4 |
| InChI | 1S/C33H30N2O2/c1-33(2,31-34-27(23-15-7-3-8-16-23)29(36-31)25-19-11-5-12-20-25)32-35-28(24-17-9-4-10-18-24)30(37-32)26-21-13-6-14-22-26/h3-22,27-30H,1-2H3/t27-,28-,29+,30+/m1/s1 |
| InChI key | ZWWGNCSTEMMQOQ-XAZDILKDSA-N |
安全信息
| 储存分类代码 | 13 - Non Combustible Solids |
| WGK | WGK 3 |
| 闪点(F) | Not applicable |
| 闪点(C) | Not applicable |
