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(11bS)-N,N-dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine

(11bS)-N,N-dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine

品牌
Sigma-Aldrich
CAS
389130-06-7
货号
685569
包装型号
规格纯度
参考价格
1184.6 *本价格含增值税费
促销
数量
-+
产品介绍:

产品说明

应用

(11bS)-N,N-dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine is a monodentate phosphoramidite (MonoPhos) chiral ligand that can be used:

  • In the Cu-catalyzed synthesis of chiral 3-(arylbut-1-yn-1-yl)silane derivatives by reacting N-tosylhydrazones with silyl-substituted alkynes via asymmetric insertion.
  • In the Rh-catalyzed asymmetric hydrogenation of R-isopropylcinnamic acid derivative, a key intermediate of renin inhibitor aliskiren.
  • In the Rh-catalyzed conjugate addition of arylboronic acids to lactones, enones, and nitroalkenes.


DSM MonoPhos Family of Highly Efficient Privileged Ligands

包装

100 mg in clear glass bottle
500 mg in amber glass bottle

法律信息

经 DSM 授权销售,仅供研究之用。

基本信息

经验(实验)分子式C22H26NO2P
分子量367.42
MDL编号MFCD04117692
PubChem化学物质编号329760980
NACRESNA.22

产品性质

旋光性[α]22/D 282.0°, c = 1 in chloroform
mp86-94 ℃
SMILES stringCN(C)P1Oc2ccc3CCCCc3c2-c4c(O1)ccc5CCCCc45
InChI1S/C22H26NO2P/c1-23(2)26-24-19-13-11-15-7-3-5-9-17(15)21(19)22-18-10-6-4-8-16(18)12-14-20(22)25-26/h11-14H,3-10H2,1-2H3
InChI keyOIZQADYWBXZQKE-UHFFFAOYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)

Sigma-Aldrich

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