产品说明
应用
(11bR)-2,6-Bis(diphenylphosphino)-N,N-dimethyldinaphtho[2,1-d:1′,2′-f]-1,3,2-dioxaphosphepin-4-amine is a phosphine-phosphoramidite ligand, which can be used in:
- The stereoselective preparation of aminoesters via rhodium-catalyzed enantioselective hydrogenation of dehydroaminoesters.
- The Rh-catalyzed asymmetric hydrogenation of N-(α-arylvinyl) acetamides.
DSM MonoPhos Family of Highly Efficient Privileged Ligands
包装
100 mg in clear glass bottle
500 mg in amber glass bottle
法律信息
经 DSM 授权销售,仅供研究使用。
基本信息
经验(实验)分子式 | C46H36NO2P3 |
分子量 | 727.70 |
MDL编号 | MFCD09750461 |
PubChem化学物质编号 | 24885751 |
NACRES | NA.22 |
产品性质
mp | 245-249 ℃ |
储存温度 | 2-8℃ |
SMILES string | CN(C)P1Oc2c(cc3ccccc3c2-c4c(O1)c(cc5ccccc45)P(c6ccccc6)c7ccccc7)P(c8ccccc8)c9ccccc9 |
InChI | 1S/C46H36NO2P3/c1-47(2)52-48-45-41(50(35-21-7-3-8-22-35)36-23-9-4-10-24-36)31-33-19-15-17-29-39(33)43(45)44-40-30-18-16-20-34(40)32-42(46(44)49-52)51(37-25-11-5-12-26-37)38-27-13-6-14-28-38/h3-32H,1-2H3 |
InChI key | JVTXDRKUFXCFCF-UHFFFAOYSA-N |
安全信息
储存分类代码 | 13 - Non Combustible Solids |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |