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2-cyanophenyl sulfofluoridate

品牌
Sigma-Aldrich
货号
ALD00420
包装型号
规格纯度
参考价格
163.66 *本价格含增值税费
促销
数量
-+
产品介绍:

产品说明

一般描述

2-Cyanophenyl sulfofluoridate is an aryl fluorosulfate. It undergoes Suzuki-Miyaura reaction with aryl boronic acid in the presence of Pd(OAc)2 and Et3N to afford the corresponding biaryl derivative. 2-Cyanophenyl sulfofluoridate can be synthesized from the reaction between phenol and sulfuryl fluoride in the presence of triethylamine.

应用

The following aryl fluorosulfate can be utilized as a cross-coupling partner in Suzuki-Miyaura reactions. The standard reaction conditions for these palladium-catalyzed C-C bond formations are ligand-free and can be performed in water, at room temperatre and are not air sensitive.

包装

500 mg in glass bottle

其他说明

Palladium-Catalyzed, Ligand-Free Suzuki Reaction in Water Using Aryl Fluorosulfates

基本信息

经验(实验)分子式C7H4FNO3S
分子量201.17
PubChem化学物质编号329772673

产品性质

质量水平100
SMILES stringO=S(F)(OC1=CC=CC=C1C#N)=O
InChI1S/C7H4FNO3S/c8-13(10,11)12-7-4-2-1-3-6(7)5-9/h1-4H
InChI keyFWHISILUCPTNBH-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P280 - P304 + P340 + P312 - P305 + P351 + P338 - P337 + P313
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码12 - Non Combustible Liquids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable

Sigma-Aldrich

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