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3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole

3,3-二甲基-1-(三氟甲基)-1,2-苯并碘氧杂戊环

品牌
Sigma-Aldrich
CAS
887144-97-0
货号
754218
包装型号
规格纯度
98%
参考价格
1512.66 *本价格含增值税费
促销
数量
-+
产品介绍:

产品说明

应用

  • Selective trifluoromethylation of 1,3-disubstituted arenes through iridium-catalyzed arene borylation and copper-catalyzed trifluoromethylation
  • Copper-catalyzed trifluoromethylation of aryl- and alkenylboronic acids with electrophilic trifluoromethylating reagent
  • Pd-catalyzed electrophilic ortho-trifluoromethylation of arenes using trifluoroacetic acid as a promotor

Used in the Preparation of
  • Trifluoromethylimidoylethyl substituted heterocycles via bis(trifluoromethylsulfonyl)amine-catalyzed Rotter type reaction of heterocycles with nitriles in presence of trifluoromethylbenziodoxole
  • Stereoselective synthesis of α-trifluoromethyl aldehydes via trimethylbenzylimidazolidinone and copper-catalyzed enantioselective α-trifluoromethylation of aldehydes with iodonium salts

包装

100 mg in clear glass bottle
500 mg in amber glass bottle

基本信息

经验(实验)分子式C10H10F3IO
分子量330.09
MDL编号MFCD10567056
PubChem化学物质编号329766407
NACRESNA.22

产品性质

质量水平100
测定98%
mp75-79 ℃
储存温度2-8℃
SMILES stringCC1(C)O[I](c2ccccc12)C(F)(F)F
InChI1S/C10H10F3IO/c1-9(2)7-5-3-4-6-8(7)14(15-9)10(11,12)13/h3-6H,1-2H3
InChI keyHVAPLSNCVYXFDQ-UHFFFAOYSA-N

Sigma-Aldrich

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