产品介绍:
产品说明
应用
RuCl[(R,R)-TsDPEN](mesitylene) may be used as a catalyst to synthesize:
- (2R,3S)-4-Benzyl-2-(hydroxyphenylmethyl)morpholin-3-one from racemic N-benzyl-2-benzoyl-3-morpholinone via dynamic kinetic resolution-based asymmetric transfer hydrogenation (ATH).
- Chiral nonracemic δ-phenylseleno alcohols from δ-phenylseleno ketones via catalytic ATH reaction.
Takasago Ligands and Complexes for Asymmetric Reactions
包装
500 mg in amber glass bottle
法律信息
与 Takasago 合作销售,仅用于研究目的。WO9720789
基本信息
经验(实验)分子式 | C30H33ClN2O2RuS |
分子量 | 622.18 |
MDL编号 | MFCD12545951 |
PubChem化学物质编号 | 329762817 |
产品性质
质量水平 | 100 |
测定 | 90% |
mp | 241-249 ℃ |
储存温度 | 2-8℃ |
SMILES string | Cc1cc(C)cc(C)c1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@@H]([C@H](N)c3ccccc3)c4ccccc4 |
InChI | 1S/C21H21N2O2S.C9H12.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-7-4-8(2)6-9(3)5-7;;/h2-15,20-21H,22H2,1H3;4-6H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m1.../s1 |
InChI key | XBNBOGZUDCYNOJ-AGEKDOICSA-M |
安全信息
储存分类代码 | 13 - Non Combustible Solids |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |
个人防护装备 | Eyeshields, Gloves, type N95 (US) |