产品介绍:
产品说明
应用
Reactant for synthesis of:
- Chiral phosphine-aminophosphine ligands for rhodium-catalyzed asymmetric hydrogenation
- Ligands for palladium-catalyzed stereoselective allylation reactions
- Ligands for enantioselective hydrogenations
- Josiphos analog as catalyst for asymmetric hydrogenation
- Ligands used in asymmetric hydrovinylation reactions
Reactant for enantioselective hydrogenation reactions catalyzed by Ru-(phosphine-oxazoline) complexes
包装
100, 500 mg in glass bottle
基本信息
经验(实验)分子式 | C16H6ClF12P |
分子量 | 492.63 |
MDL编号 | MFCD01630852 |
PubChem化学物质编号 | 329761683 |
NACRES | NA.22 |
产品性质
reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: ligand |
质量水平 | 100 |
mp | 25-29 ℃ |
官能团 | phosphine |
SMILES string | FC(F)(F)c1cc(cc(c1)C(F)(F)F)P(Cl)c2cc(cc(c2)C(F)(F)F)C(F)(F)F |
InChI | 1S/C16H6ClF12P/c17-30(11-3-7(13(18,19)20)1-8(4-11)14(21,22)23)12-5-9(15(24,25)26)2-10(6-12)16(27,28)29/h1-6H |
InChI key | DFZQEHBNAJGDCT-UHFFFAOYSA-N |
安全信息
象形图 | |
警示用语: | Danger |
危险声明 | H261 - H314 |
预防措施声明 | P231 + P232 - P280 - P305 + P351 + P338 - P310 - P422 |
危险分类 | Skin Corr. 1B - Water-react. 3 |
储存分类代码 | 4.3 - Hazardous materials, which set free flammable gases upon contact with water |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |
个人防护装备 | Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges |