产品介绍：
产品说明
一般描述
Methanesulfonylacetone is a sulfonyl group-containing active methylene compound. It can react with Baylis–Hillman acetates in dimethylformamide/potassium carbonate system to form ortho-hydroxyacetophenone derivatives.
应用
Methanesulfonylacetone may be used in the preparation of 6-bromo-3-methanesulfonyl-2-methyl-quinolin-4-ol.
Reactant for:
- Stereoselective preparation of chiral cyclic ketones
- Preparation of poly-substituted pyridines
- Multicomponent cyclocondensation with aldehydes and aminoazoles
- Gold-catalyzed Friedlander cyclocondensation reaction
- Radical homoallylation reactions
包装
10 g in glass bottle
基本信息
| 线性分子式 | CH3C(O)CH2SO2CH3 |
| 分子量 | 136.17 |
| EC 号 | 225-665-6 |
| MDL编号 | MFCD00014745 |
| PubChem化学物质编号 | 24878779 |
| NACRES | NA.22 |
产品性质
| 质量水平 | 100 |
| 测定 | 97% |
| 形式 | powder or crystals |
| mp | 48-52 ℃ (lit.) |
| SMILES string | CC(=O)CS(C)(=O)=O |
| InChI | 1S/C4H8O3S/c1-4(5)3-8(2,6)7/h3H2,1-2H3 |
| InChI key | NWEYGXQKFVGUFR-UHFFFAOYSA-N |
安全信息
| 储存分类代码 | 13 - Non Combustible Solids |
| WGK | WGK 3 |
| 闪点(F) | Not applicable |
| 闪点(C) | Not applicable |
| 个人防护装备 | Eyeshields, Gloves, type N95 (US) |
