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1,1′-Bis(phenylphosphinidene)ferrocene

1,1′-双(苯基亚膦基)二茂铁

品牌
Sigma-Aldrich
CAS
72954-06-4
货号
567159
包装型号
规格纯度
97%
参考价格
1272.49 *本价格含增值税费
促销
数量
-+
产品介绍:

产品说明

应用

Reactant for:

  • Preparation of macrocyclic tridentate ferrocenylphosphine ligands
  • Preparation of phosphorus-bridged ferrocenophane with syn and anti conformations
  • Reaction with phenyllithium and chlorophosphine to give ferrocenediyl ligand and its rhodium complex catalyst for selective hydroformylation of alkenes
  • Ring-opening reactions via ring slippage
  • Preparation of palladium chloro (ferrocene-bridged)phosphine-phosphonite complex for catalysis of Heck reaction of iodobenzene with Me acrylate

包装

1 g in glass bottle

基本信息

线性分子式C5H4PC6H5C5H4Fe
分子量292.09
MDL编号MFCD04974069
PubChem化学物质编号24880349
NACRESNA.22

产品性质

质量水平100
测定97%
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
mp88-92 ℃ (lit.)
官能团phosphine
储存温度2-8℃
SMILES string[Fe].[CH]1[CH][CH][C]([CH]1)P([C]2[CH][CH][CH][CH]2)c3ccccc3
InChI1S/C16H13P.Fe/c1-2-8-14(9-3-1)17(15-10-4-5-11-15)16-12-6-7-13-16;/h1-13H;
InChI keyHKOUDNXXOXEYNZ-UHFFFAOYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)

Sigma-Aldrich

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