产品介绍：
产品说明
一般描述
与 Solvias AG 联合销售
应用
(R)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis[bis(3,5-di-tert-butylphenyl)phosphine] can be used as a ligand to prepare:
- 1,2-Dihydropyridines through Rh-catalyzed cycloaddition of diynes to sulfonimines.
- Enantiorich disubstituted γ-lactams via intramolecular allylic alkylation reaction using Pd catalyst.
- A Ru-metal complex, which acts as a hydrogenation catalyst applicable in the synthesis of an organic building block (S)-3-fluoromethyl-γ-butyrolactone.
Atropisomeric MeOBIPHEP ligands
包装
1, 5 g in glass bottle
100, 500 mg in glass bottle
Bottomless glass bottle. Contents are inside inserted fused cone.
基本信息
| 经验(实验)分子式 | C70H96O2P2 |
| 分子量 | 1031.46 |
| MDL编号 | MFCD09753001 |
| PubChem化学物质编号 | 329753371 |
| NACRES | NA.22 |
产品性质
| 质量水平 | 100 |
| 测定 | ≥97% |
| 光学纯度 | ee: ≥99% |
| SMILES string | COc1cccc(P(c2cc(cc(c2)C(C)(C)C)C(C)(C)C)c3cc(cc(c3)C(C)(C)C)C(C)(C)C)c1-c4c(OC)cccc4P(c5cc(cc(c5)C(C)(C)C)C(C)(C)C)c6cc(cc(c6)C(C)(C)C)C(C)(C)C |
| InChI | 1S/C70H96O2P2/c1-63(2,3)45-33-46(64(4,5)6)38-53(37-45)73(54-39-47(65(7,8)9)34-48(40-54)66(10,11)12)59-31-27-29-57(71-25)61(59)62-58(72-26)30-28-32-60(62)74(55-41-49(67(13,14)15)35-50(42-55)68(16,17)18)56-43-51(69(19,20)21)36-52(44-56)70(22,23)24/h27-44H,1-26H3 |
| InChI key | PBYRAYONARLAQJ-UHFFFAOYSA-N |
安全信息
| 储存分类代码 | 13 - Non Combustible Solids |
| WGK | WGK 3 |
| 闪点(F) | Not applicable |
| 闪点(C) | Not applicable |
| 个人防护装备 | Eyeshields, Gloves, type N95 (US) |
