产品介绍：
产品说明
应用
Evan′s chiral auxiliary (4R,5S)-(+)-4-Methyl-5-phenyl-2-oxazolidinone reacts with carboxylic acids to produce corresponding acyl derivatives in the presence of a diisopropylcarbodiimide reagent. It can also employed in the preparation of N-sulfinyloxazolidinone reagent (chiral sulfinyl transfer reagent), which reacts with nucleophiles such as Grignard reagents, enolates, and metalated amides to produce the chiral sulfoxides, sulfinate esters, and sulfonamides.
包装
5, 25 g in glass bottle
基本信息
| 经验(实验)分子式 | C10H11NO2 |
| 分子量 | 177.20 |
| Beilstein | 1211705 |
| MDL编号 | MFCD00010845 |
| PubChem化学物质编号 | 24858003 |
| NACRES | NA.22 |
产品性质
| 质量水平 | 100 |
| 测定 | 99% |
| 旋光性 | [α]18/D +168°, c = 2 in chloroform |
| 光学纯度 | ee: 98% (GLC) |
| mp | 121-123 ℃ (lit.) |
| SMILES string | C[C@H]1NC(=O)O[C@H]1c2ccccc2 |
| InChI | 1S/C10H11NO2/c1-7-9(13-10(12)11-7)8-5-3-2-4-6-8/h2-7,9H,1H3,(H,11,12)/t7-,9-/m1/s1 |
| InChI key | PPIBJOQGAJBQDF-VXNVDRBHSA-N |
安全信息
| 储存分类代码 | 11 - Combustible Solids |
| WGK | WGK 3 |
| 闪点(F) | Not applicable |
| 闪点(C) | Not applicable |
| 个人防护装备 | Eyeshields, Gloves, type N95 (US) |
