产品说明
应用
(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) may be used as a catalyst for the Jacobsen′s hydrolytic kinetic resolution of racemic epoxides, which is a key step during the multi-step synthesis of (+)-patulolide C, macrosphelides(I and G), (-)-(3S,6R)-3,6-dihydroxy-10-methylundecanoic acid, dodoneine, epidodoneine and protein kinase C epsilon (PKCe) inhibitors.
用于末端环氧化物的水解动力学拆分和内消旋环氧化物不对称开环的催化剂。
包装
1, 5, 25 g in glass bottle
法律信息
经 Shasun Chemicals and Drugs Limited 授权销售。
基本信息
线性分子式 | [[[(CH3)3C]2C6H2-2-(O-)CH=N]2C6H10]Co |
分子量 | 603.74 |
MDL编号 | MFCD01631278 |
PubChem化学物质编号 | 24871025 |
NACRES | NA.22 |
产品性质
质量水平 | 200 |
mp | >350 ℃ (lit.) |
SMILES string | CC(C)(C)c1cc2C=[N@@H]3[C@H]4CCCC[C@@H]4[N@H]5=Cc6cc(cc(c6O[Co]35Oc2c(c1)C(C)(C)C)C(C)(C)C)C(C)(C)C |
InChI | 1S/C36H54N2O2.Co/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;/h17-22,29-30,39-40H,13-16H2,1-12H3;/q;+2/p-2/b37-21+,38-22+;/t29-,30-;/m0./s1 |
InChI key | ZFWPDJKMASHRPT-IKKUFEJKSA-L |
安全信息
储存分类代码 | 13 - Non Combustible Solids |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |
个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |