产品介绍：
产品说明
应用
Methyl P,P-bis(2,2,2-trifluoroethyl)phosphonoacetate can be used:
- In one of the key synthetic steps for the preparation of trans-hydrindanes and (R)-(+)-umbelactone.
- To prepare a cis-olefinic ester derivative by Still–Gennari olefination of an aldehyde derivative using 18-crown ether and potassium bis(trimethylsilyl)amide (KHMDS).
- In the synthesis of (−)-(6S,2′S)-epi cryptocaryalactone.
包装
5 g in glass bottle
基本信息
| 线性分子式 | CH3O2CCH2P(O)(OCH2CF3)2 |
| 分子量 | 318.11 |
| Beilstein | 3594044 |
| MDL编号 | MFCD00009901 |
| PubChem化学物质编号 | 24856576 |
| NACRES | NA.22 |
产品性质
| 测定 | 95% |
| 形式 | liquid |
| reaction suitability | reaction type: C-C Bond Formation |
| 折射率 | n |
| 密度 | 1.504 g/mL at 25 ℃ (lit.) |
| SMILES string | COC(=O)CP(=O)(OCC(F)(F)F)OCC(F)(F)F |
| InChI | 1S/C7H9F6O5P/c1-16-5(14)2-19(15,17-3-6(8,9)10)18-4-7(11,12)13/h2-4H2,1H3 |
| InChI key | PVSJXEDBEXYLML-UHFFFAOYSA-N |
安全信息
| 象形图 |  |
| 警示用语： | Warning |
| 危险声明 | H315 - H319 - H335 |
| 预防措施声明 | P302 + P352 - P305 + P351 + P338 |
| 危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
| 靶器官 | Respiratory system |
| 储存分类代码 | 10 - Combustible liquids |
| WGK | WGK 3 |
| 闪点(F) | 230.0 °F - closed cup |
| 闪点(C) | 110 ℃ - closed cup |
| 个人防护装备 | Eyeshields, Gloves, type ABEK (EN14387) respirator filter |
