产品介绍:
产品说明
应用
- Sodium bis(trimethylsilyl)amide, also known as NaHMDS, is a metal dialkylamide reagent that combines both high basicity and nucleophilicity. It is a general reagent used for the enolization of carbonyl compounds.
- It can be used to prepare phosphonium ylides in Wittig reaction.
- NaHMDS solution can also be used as a source of nitrogen in aminomethylation and in the synthesis of primary amines from the corresponding alkyl halides.
包装
500 mL in Sure/Seal™
其他说明
根据要求提供批量采购价
基本信息
线性分子式 | [(CH3)3Si]2NNa |
分子量 | 183.37 |
Beilstein | 3629917 |
MDL编号 | MFCD00009835 |
PubChem化学物质编号 | 57652836 |
NACRES | NA.22 |
产品性质
等级 | produced by Wacker Chemie AG, Burghausen, Germany |
质量水平 | 200 |
形式 | liquid |
浓度 | 40% in THF |
SMILES string | C[Si](C)(C)N([Na])[Si](C)(C)C |
InChI | 1S/C6H18NSi2.Na/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1 |
InChI key | WRIKHQLVHPKCJU-UHFFFAOYSA-N |
安全信息
象形图 | |
警示用语: | Danger |
危险声明 | H225 - H314 - H335 - H336 - H351 |
预防措施声明 | P201 - P210 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 |
危险分类 | Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B |
补充剂危害 | EUH014 - EUH018 - EUH019 |
储存分类代码 | 3 - Flammable liquids |
WGK | WGK 2 |
闪点(F) | 1.4 °F - closed cup |
闪点(C) | -17 ℃ - closed cup |
个人防护装备 | Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter |