产品介绍:
产品说明
一般描述
Chlorotris(trimethylsilyl)silane is an organosilicon reagent, which is generally employed in the protection of alcohols. It is also used to prepare organometallic reagents, silyl enol ethers, and novel polymers/materials.
应用
Super Silyl Protecting Groups
Used for:
- Insertion into a P-P bond
- Diastereoselective aldol and cascade reactions
- Preparation of hypersilyl substituted monophosphines and diphosphines
包装
10, 25 g in poly bottle
基本信息
线性分子式 | [(CH3)3Si]3SiCl |
分子量 | 283.11 |
MDL编号 | MFCD01321222 |
PubChem化学物质编号 | 24865643 |
NACRES | NA.22 |
产品性质
质量水平 | 100 |
测定 | 97% |
mp | 50-52 ℃ (lit.) |
SMILES string | C[Si](C)(C)[Si](Cl)([Si](C)(C)C)[Si](C)(C)C |
InChI | 1S/C9H27ClSi4/c1-11(2,3)14(10,12(4,5)6)13(7,8)9/h1-9H3 |
InChI key | HCOROOJWVHFMRJ-UHFFFAOYSA-N |
安全信息
象形图 | |
警示用语: | Danger |
危险声明 | H228 - H261 - H315 - H319 - H335 |
预防措施声明 | P210 - P231 + P232 - P302 + P352 - P305 + P351 + P338 |
危险分类 | Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3 - Water-react. 3 |
靶器官 | Respiratory system |
补充剂危害 | EUH029 |
储存分类代码 | 4.3 - Hazardous materials, which set free flammable gases upon contact with water |
WGK | WGK 3 |
闪点(F) | 87.8 °F - closed cup |
闪点(C) | 31 ℃ - closed cup |
个人防护装备 | Eyeshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges |