产品介绍：
产品说明
应用
Nickel(II) bromide 2-methoxyethyl ether complex can be used as a catalyst to prepare:
- Hindered diarylmethanols and benzylic alcohols by the addition of aryl halides to various aldehydes in the presence of Zn as a reducing agent.
- Benzene-fused cyclic compounds via reductive dicarbofunctionalization of unactivated alkenes using less reactive benzyl chlorides.
- Benzylboron derivatives via C-C cross-coupling reaction between substituted 5-bromo-3-methoxy-2-(trimethylsilyl)phenyl triflate and bromomethylboronic acid pinacol ester.
- N-(Hetero)aryl sulfamides by N-arylation of sulfamides with aryl bromides in the presence of a photosensitizer.
包装
5 g in glass bottle
基本信息
| 线性分子式 | NiBr2 · O(CH2CH2OCH3)2 |
| 分子量 | 352.67 |
| MDL编号 | MFCD00274339 |
| PubChem化学物质编号 | 24869583 |
| NACRES | NA.23 |
产品性质
| 形式 | powder |
| 质量水平 | 100 |
| reaction suitability | reagent type: catalyst core: nickel |
| SMILES string | Br[Ni]Br.COCCOCCOC |
| InChI | 1S/C6H14O3.2BrH.Ni/c1-7-3-5-9-6-4-8-2;;;/h3-6H2,1-2H3;2*1H;/q;;;+2/p-2 |
| InChI key | RRSIMIHTHWYRRA-UHFFFAOYSA-L |
安全信息
| 象形图 |   |
| 警示用语： | Danger |
| 危险声明 | H228 - H302 + H312 + H332 - H315 - H319 - H335 |
| 预防措施声明 | P210 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338 |
| 危险分类 | Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3 |
| 靶器官 | Respiratory system |
| 储存分类代码 | 4.1B - Flammable solid hazardous materials |
| WGK | WGK 3 |
| 闪点(F) | Not applicable |
| 闪点(C) | Not applicable |
| 个人防护装备 | Eyeshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges |
