产品说明

一般描述

Benzyloxyacetone (α-Benzyloxyacetone) is an α-substituted acetone. It undergoes direct aldol reaction with 4-nitrobenzaldehyde in the presence of (S)-BINAM-L-prolinamide/benzoic acid to form predominantly the syn-diasteroisomer.

应用

Benzyloxyacetone (1-Benzyloxy-2-propanone) may be used in the synthesis of:

• 7-benzyloxy-6-methyl-5-hepten-1-yne
• (Z)-2-methylhept-2-en-6-yn-1-o1
• (S)-(+)-1,2-propanediol, 1-benzyl ether

It may be used as a starting material in synthesizing (2S,4RS)-4-acetoxy-2-[(benzyloxy)methyl]-2-methyldioxolane and (2R,4RS)-4-acetoxy-2-[(benzyloxy)methyl]-2-methyldioxolane.

包装

5 g in glass bottle

基本信息

线性分子式	C6H5CH2OCH2COCH3
分子量	164.20
MDL编号	MFCD01863536
PubChem化学物质编号	24872460
NACRES	NA.22

产品性质

测定	90%
杂质	3% (benzyloxy)acetic acid 3% benzyl alcohol
折射率	n20/D 1.512 (lit.)
bp	259 ℃ (lit.)
密度	1.04 g/mL at 25 ℃ (lit.)
SMILES string	CC(=O)COCc1ccccc1
InChI	1S/C10H12O2/c1-9(11)7-12-8-10-5-3-2-4-6-10/h2-6H,7-8H2,1H3
InChI key	YHMRKVGUSQWDGZ-UHFFFAOYSA-N

安全信息

储存分类代码	10 - Combustible liquids
WGK	WGK 3
闪点(F)	230.0 °F - closed cup
闪点(C)	110 ℃ - closed cup
个人防护装备	Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)