产品介绍：
产品说明
一般描述
(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride is a metal-salen complex that can catalyze a variety of asymmetric transformations.
应用
Reactant involved in:
- Studies of intercalative binding with ct-DNA and radical scavenging antioxidant activity
- Immobilization on phenoxy-modified zirconium poly(styrenephenylvinylphosphonate)
- Synthesis of derivatvies for studies of conformational models of enantioselective reactions
Catalyst involved in:
- Asymmetric epoxidation of olefins
- Immobilization on ionic liquid modified mesoporous silica for oxidative kinetic resolution of racemic secondary alcohols†
- Immobilization on diamine modified zirconium olig-styrenyl phosphonate hydrogen phosphate for epoxidation of styrene
非官能化烯烃类的 Salen (Mn)-催化不对称环氧化反应。获得各种底物(特别是顺式-烯烃)的高对映立体选择性和产量。一些用途包括合成紫杉醇侧链和顺式-1-氨基-2-茚醇。Jacobsen 催化剂还用于硅烯醇醚的不对称 α-羟基化。用于各种烯烃不对称环氧化反应的催化剂。
包装
1, 5, 25 g in glass bottle
法律信息
经 Shasun Chemicals and Drugs Limited 授权，使用 Jacobsen HKR 技术制造。
基本信息
| 线性分子式 | [[[(CH3)3C]2C6H2-2-(O-)CH=N]2C6H10]MnCl |
| 分子量 | 635.20 |
| MDL编号 | MFCD02101663 |
| PubChem化学物质编号 | 24865247 |
| NACRES | NA.22 |
产品性质
| 质量水平 | 200 |
| mp | 330-332 ℃ (lit.) |
| SMILES string | CC(C)(C)c1cc2C=[N@@H]3[C@H]4CCCC[C@@H]4[N@H]5=Cc6cc(cc(c6O[Mn]35(Cl)Oc2c(c1)C(C)(C)C)C(C)(C)C)C(C)(C)C |
| InChI | 1S/C36H54N2O2.ClH.Mn/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;;/h17-22,29-30,39-40H,13-16H2,1-12H3;1H;/q;;+3/p-3/b37-21+,38-22+;;/t29-,30-;;/m0../s1 |
| InChI key | LJVAWOSDJSQANR-RUIQGICGSA-K |
安全信息
| 象形图 |  |
| 警示用语： | Warning |
| 危险声明 | H315 - H319 - H335 |
| 预防措施声明 | P302 + P352 - P305 + P351 + P338 |
| 危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
| 靶器官 | Respiratory system |
| 储存分类代码 | 11 - Combustible Solids |
| WGK | WGK 3 |
| 闪点(F) | Not applicable |
| 闪点(C) | Not applicable |
| 个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
