产品介绍：
产品说明
应用
Trifluoromethanesulfonic anhydride can be used in the preparation of azido sugars such as 6-azido fucose. It can also be used as a promoter for the Friedel-Crafts acylation of aromatic compounds with carboxylic acids in the absence of catalyst.
Tf2O in combination with:
- Diphenyl sulfoxide, forms an efficient promoter system for the activation of thioglycosides for glycosylation reactions.
- 2-chloropyridine, can be used for secondary amide activation.
- Potassium iodide, can effectively mediate the deoxygenation of sulfoxides to form sulfides.
- Hydrogen peroxide, for the selective oxidation of sulfanes to sulfoxides in the presence of oxidatively sensitive functional groups.
Tf2O can react with:
- Ketones in the presence of a base to form vinyl triflates.
- Magnesium alkoxides to form corresponding symmetrical or unsymmetrical ethers.
- Sodium azide for the in situ preparation of triflyl azide.
糖基化合成催化剂糖基化合成试剂
甘露三嗪甲基脲酸酯供体糖基化空间选择性合成试剂
异丙基羟基糖直接糖基化活化剂
包装
100 mL in glass bottle
其他说明
亲电子三氟甲磺酰基的来源。综述
基本信息
| 线性分子式 | (CF3SO2)2O |
| 分子量 | 282.14 |
| Beilstein | 1813600 |
| EC 号 | 206-616-8 |
| MDL编号 | MFCD00000408 |
| PubChem化学物质编号 | 329770073 |
| NACRES | NA.22 |
产品性质
| 质量水平 | 200 |
| 蒸汽密度 | 5.2 (vs air) |
| 蒸汽压 | 8 mmHg ( 20 ℃) |
| 等级 | purum |
| 测定 | ≥98.0% (T) |
| 形式 | liquid |
| 折射率 | n |
| bp | 81-83 ℃ (lit.) |
| 密度 | 1.677 g/mL at 25 ℃ (lit.) |
| SMILES string | FC(F)(F)S(=O)(=O)OS(=O)(=O)C(F)(F)F |
| InChI | 1S/C2F6O5S2/c3-1(4,5)14(9,10)13-15(11,12)2(6,7)8 |
| InChI key | WJKHJLXJJJATHN-UHFFFAOYSA-N |
安全信息
| 象形图 |    |
| 警示用语： | Danger |
| 危险声明 | H272 - H302 - H314 - H335 |
| 预防措施声明 | P210 - P220 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338 |
| 危险分类 | Acute Tox. 4 Oral - Eye Dam. 1 - Ox. Liq. 2 - Skin Corr. 1B - STOT SE 3 |
| 靶器官 | Respiratory system |
| 补充剂危害 | EUH014 |
| 储存分类代码 | 5.1B - Oxidizing hazardous materials |
| WGK | WGK 3 |
| 个人防护装备 | Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter |
