产品介绍：
产品说明
应用
Reacts with halotriazines to produce conductive, anisotropic carbon-nitrogen materials.
Lithium (trimethylsilyl)acetylide can be used as a reagent:
- In the transmetalation and nucleophilic displacement reactions.
- To prepare propargylic alcohol derivatives by reacting with aldehydes and ketones.
- To synthesize α,βynones by treating with Weinreb amide or with isoxazolidide.
- Along with Grignard reagent to convert γ- and δ-thiolactams to thioiminium salts, which are employed as key intermediates to produce disubstituted pyrrolidines.
包装
4×25, 50, 500 mL in Sure/Seal™
The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
法律信息
Sure/Seal is a trademark of sigma-aldrich Co. LLC
基本信息
| 线性分子式 | (CH3)3SiC≡CLi |
| 分子量 | 104.15 |
| Beilstein | 3587411 |
| MDL编号 | MFCD00075059 |
| PubChem化学物质编号 | 24860321 |
| NACRES | NA.22 |
产品性质
| 质量水平 | 100 |
| 浓度 | 0.5 M in THF |
| 密度 | 0.88 g/mL at 25 ℃ |
| SMILES string | [Li]C#C[Si](C)(C)C |
| InChI | 1S/C5H9Si.Li/c1-5-6(2,3)4;/h2-4H3; |
| InChI key | ZVXXEONXFWSCIZ-UHFFFAOYSA-N |
安全信息
| 象形图 |     |
| 警示用语： | Danger |
| 危险声明 | H225 - H302 - H314 - H335 - H351 |
| 预防措施声明 | P210 - P260 - P280 - P305 + P351 + P338 - P370 + P378 - P403 + P235 |
| 危险分类 | Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 |
| 靶器官 | Respiratory system |
| 补充剂危害 | EUH019 |
| 储存分类代码 | 3 - Flammable liquids |
| WGK | WGK 3 |
| 闪点(F) | -9.4 °F - closed cup |
| 闪点(C) | -23 ℃ - closed cup |
| 个人防护装备 | Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter |
