产品说明
一般描述
1-Bromo-3-(trifluoromethoxy)benzene undergoes Diels-Alder reaction with lithium diisopropylamide (LDA) in THF and furan, to yield the corresponding 1,4-dihydro-1,4-epoxy-5- or 6-(trifluoromethoxy)naphthalenes.
应用
1-Bromo-3-(trifluoromethoxy)benzene may be used in the preparation of 1,2-dehydro-3-(trifluoromethoxy)benzene. It may be used in the synthesis of new electronically deficient atropisomeric diphosphine ligand (S)-CF3O-BiPhep [2,2′-bis(diphenylphosphino)-6,6′-ditrifluoromethoxy-1,1′-biphenyl].
包装
5 g in ampule
基本信息
线性分子式 | BrC6H4OCF3 |
分子量 | 241.01 |
MDL编号 | MFCD00040943 |
PubChem化学物质编号 | 24861214 |
NACRES | NA.22 |
产品性质
质量水平 | 100 |
测定 | 99% |
折射率 | n |
密度 | 1.62 g/mL at 25 ℃ (lit.) |
SMILES string | FC(F)(F)Oc1cccc(Br)c1 |
InChI | 1S/C7H4BrF3O/c8-5-2-1-3-6(4-5)12-7(9,10)11/h1-4H |
InChI key | WVUDHWBCPSXAFN-UHFFFAOYSA-N |
安全信息
储存分类代码 | 10 - Combustible liquids |
WGK | WGK 3 |
闪点(F) | 145.4 °F - closed cup |
闪点(C) | 63 ℃ - closed cup |
个人防护装备 | Eyeshields, Gloves, multi-purpose combination respirator cartridge (US) |