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(R)-(+)-Styrene oxide

(R)-(+)-氧化苯乙烯

品牌
Sigma-Aldrich
CAS
20780-53-4
货号
540099
规格纯度
97%, optical purity ee: 97% (GLC)
参考价格
735.19 *本价格含增值税费
促销
数量
-+
产品介绍:

产品说明

应用

Used to produce a homologated epoxide as part of a synthetic approach to (+)-allosedamine.
(R)-(+)-Styrene oxide can be used:

  • As a chiral initiator in the synthesis of 5-pyrimidyl alkanol from its corresponding aldehyde using diisopropylzinc.
  • As a substrate in the stereoselective intermolecular O-alkylation of phenols with epoxides via Friedel–Crafts-type reaction.
  • As a substrate in the ring-opening reactions of epoxides with alcohols, carboxylic acids, and thiols using the AlPW12O40 catalyst.

包装

5 g in glass bottle
25 g in poly bottle

法律信息

经 Shasun Chemicals and Drugs Limited 授权,使用 Jacobsen HKR 技术制造。

基本信息

经验(实验)分子式C8H8O
分子量120.15
Beilstein1984
MDL编号MFCD00066210
PubChem化学物质编号24878440
NACRESNA.22

产品性质

质量水平100
测定97%
旋光性[α]20/D +33°, neat
光学纯度ee: 97% (GLC)
expl. lim.~22 %
折射率n20/D 1.534 (lit.)
bp89-90 ℃/23 mmHg (lit.)
密度1.051 g/mL at 25 ℃ (lit.)
SMILES stringC1O[C@@H]1c2ccccc2
InChI1S/C8H8O/c1-2-4-7(5-3-1)8-6-9-8/h1-5,8H,6H2/t8-/m0/s1
InChI keyAWMVMTVKBNGEAK-QMMMGPOBSA-N

安全信息

象形图GHS07GHS08
警示用语:Danger
危险声明H312 - H319 - H350
预防措施声明P202 - P264 - P280 - P302 + P352 + P312 - P305 + P351 + P338 - P308 + P313
危险分类Acute Tox. 4 Dermal - Carc. 1B - Eye Irrit. 2
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
闪点(F)176.0 °F - closed cup
闪点(C)80 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Sigma-Aldrich

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