产品介绍:
产品说明
应用
(R, R)-DIPAMP can be used:
- As a catalyst in the enantioselective [3+2] cycloaddition of γ-substituted allenoates with β-perfluoroalkyl enones and 3-butynoates with electron-deficient olefins to yield substituted cyclopentenes.
- To prepare its rhodium metal complexes, which are used as catalysts in asymmetric hydrogenation reactions.
包装
100, 500 mg in amber glass bottle
基本信息
线性分子式 | [CH3OC6H4P(C6H5)CH2-]2 |
分子量 | 458.47 |
MDL编号 | MFCD05863546 |
PubChem化学物质编号 | 329761951 |
NACRES | NA.22 |
产品性质
质量水平 | 100 |
测定 | 95% |
旋光性 | [α]22/D −81°, c = 1 in chloroform |
mp | 102-106 ℃ (lit.) |
SMILES string | COc1ccccc1P(CCP(c2ccccc2)c3ccccc3OC)c4ccccc4 |
InChI | 1S/C28H28O2P2/c1-29-25-17-9-11-19-27(25)31(23-13-5-3-6-14-23)21-22-32(24-15-7-4-8-16-24)28-20-12-10-18-26(28)30-2/h3-20H,21-22H2,1-2H3/t31-,32-/m1/s1 |
InChI key | QKZWXPLBVCKXNQ-ROJLCIKYSA-N |
安全信息
象形图 | |
警示用语: | Warning |
危险声明 | H315 - H319 - H335 - H413 |
预防措施声明 | P273 - P302 + P352 - P305 + P351 + P338 |
危险分类 | Aquatic Chronic 4 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
靶器官 | Respiratory system |
储存分类代码 | 11 - Combustible Solids |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |
个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |