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(S)-(-)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine)

(S)-(-)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine)

品牌
Sigma-Aldrich
CAS
133545-17-2
货号
29511
规格纯度
≥97%, optical purity ee: ≥99%
参考价格
126665 *本价格含增值税费
促销
数量
-+
产品介绍:

产品说明

一般描述

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

应用

Ligand for ruthenium-catalyzed greener amine synthesis by enamine reduction with hydrogen gas.

Asymmetric Synthesis of (S)-3-Amino-4-methoxy-butan-1-ol by Way of Reductive Amination
Atropisomeric MeOBIPHEP ligands

  • C–C coupling reactions
  • Ligand for palladium-catalyzed intramolecular allylic alkylation of unsaturated amides
  • Enantioselective hydrogenation of a-amino-ß-keto ester hydrochlorides catalyzed by an iridium complex
  • Asymmetric hydrogenation of aromatic ketones

包装

1, 5 g in glass bottle
500 mg in glass bottle
Bottomless glass bottle. Contents are inside inserted fused cone.

基本信息

经验(实验)分子式C38H32O2P2
分子量582.61
Beilstein4790083
MDL编号MFCD03095430
PubChem化学物质编号24857759
NACRESNA.22

产品性质

质量水平100
测定≥97%
光学纯度ee: ≥99%
环保替代产品特性Catalysis
Learn more about the Principles of Green Chemistry.
环保替代产品分类Aligned
SMILES stringCOc1cccc(P(c2ccccc2)c3ccccc3)c1-c4c(OC)cccc4P(c5ccccc5)c6ccccc6
InChI1S/C38H32O2P2/c1-39-33-25-15-27-35(41(29-17-7-3-8-18-29)30-19-9-4-10-20-30)37(33)38-34(40-2)26-16-28-36(38)42(31-21-11-5-12-22-31)32-23-13-6-14-24-32/h3-28H,1-2H3
InChI keyKRJVQCZJJSUHHO-UHFFFAOYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)

Sigma-Aldrich

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