产品介绍：
产品说明
应用
Tris(triphenylphosphine)ruthenium(II) dichloride or [RuCl2(PPh3)3] can be used as a catalyst to synthesize:
- Functionalized alcohols by C-C cross-coupling reaction between different alcohols via sp3 C-H bond activation of primary alcohols in the presence of Lewis acid.
- Furan derivatives from allenyl sulfides via 1,4 migration of the sulfanyl group.
- 1,3-diphenylpropan-1-one by alkylation of acetophenone with benzyl alcohol via C-C bond formation.
- Vinyl chloride monomer by hydrochlorination reaction of acetylene.
RuCl2(PPh3)3 can also be used as a catalyst in the cyclization, isomerization, reduction, oxidation, and cross-coupling reactions of a variety of organic products. Hydrogenation of nitro groups, imines, and ketones, as well as selective oxidation of alcohols are also possible in the presence of this catalyst.
包装
1, 5, 25 g in glass bottle
基本信息
| 线性分子式 | [(C6H5)3P]3RuCl2 |
| 分子量 | 958.83 |
| Beilstein | 4935939 |
| EC 号 | 239-569-7 |
| MDL编号 | MFCD00013077 |
| PubChem化学物质编号 | 24853394 |
| NACRES | NA.22 |
产品性质
| 质量水平 | 100 |
| 测定 | 97% |
| reaction suitability | core: ruthenium reagent type: catalyst reaction type: C-H Activation |
| SMILES string | Cl[Ru]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9 |
| InChI | 1S/3C18H15P.2ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h3*1-15H;2*1H;/q;;;;;+2/p-2 |
| InChI key | WIWBLJMBLGWSIN-UHFFFAOYSA-L |
安全信息
| 储存分类代码 | 13 - Non Combustible Solids |
| WGK | WGK 3 |
| 闪点(F) | Not applicable |
| 闪点(C) | Not applicable |
| 个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
