产品说明

应用

Tris(triphenylphosphine)ruthenium(II) dichloride or [RuCl₂(PPh₃)₃] can be used as a catalyst to synthesize:

• Functionalized alcohols by C-C cross-coupling reaction between different alcohols via sp³ C-H bond activation of primary alcohols in the presence of Lewis acid.
• Furan derivatives from allenyl sulfides via 1,4 migration of the sulfanyl group.
• 1,3-diphenylpropan-1-one by alkylation of acetophenone with benzyl alcohol via C-C bond formation.
• Vinyl chloride monomer by hydrochlorination reaction of acetylene.

RuCl₂(PPh₃)₃ can also be used as a catalyst in the cyclization, isomerization, reduction, oxidation, and cross-coupling reactions of a variety of organic products. Hydrogenation of nitro groups, imines, and ketones, as well as selective oxidation of alcohols are also possible in the presence of this catalyst.

包装

1, 5, 25 g in glass bottle

基本信息

线性分子式	[(C6H5)3P]3RuCl2
分子量	958.83
Beilstein	4935939
EC 号	239-569-7
MDL编号	MFCD00013077
PubChem化学物质编号	24853394
NACRES	NA.22

产品性质

质量水平	100
测定	97%
reaction suitability	core: ruthenium reagent type: catalyst reaction type: C-H Activation
SMILES string	Cl[Ru]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
InChI	1S/3C18H15P.2ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h3*1-15H;2*1H;/q;;;;;+2/p-2
InChI key	WIWBLJMBLGWSIN-UHFFFAOYSA-L

安全信息

储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves