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(Triethylsilyl)acetylene

三乙基乙炔基硅烷

品牌
Sigma-Aldrich
CAS
1777-03-3
货号
346977
包装型号
规格纯度
97%
参考价格
818.19 *本价格含增值税费
促销
数量
-+
产品介绍:

产品说明

一般描述

(Triethylsilyl)acetylene, a bulky trialkylsilyl-protected alkyne, undergoes Cadiot-Chodkiewicz cross-coupling reaction with various bromoalkynes to yield synthetically useful unsymmetrical diynes. Rhodium-catalyzed dimerization of (triethylsilyl)acetylene has been reported.

应用

(Triethylsilyl)acetylene may be used in the synthesis of triethylsilylethynyl anthradithiophenes, such as :

  • 2,8-dimethyl-5,11-bis(triethylsilylethynyl)ADT (ADT= anthradithiophene)
  • 2,8-diethyl-5,11-bis(triethylsilylethynyl)ADT
  • 2,8-dipropyl-5,11-bis(triethylsilylethynyl)ADT

包装

5 g in glass bottle

基本信息

线性分子式(C2H5)3SiC≡CH
分子量140.30
Beilstein1743814
MDL编号MFCD00075373
PubChem化学物质编号24861453
NACRESNA.22

产品性质

质量水平100
测定97%
折射率n20/D 1.433 (lit.)
密度0.783 g/mL at 25 ℃ (lit.)
SMILES stringCC[Si](CC)(CC)C#C
InChI1S/C8H16Si/c1-5-9(6-2,7-3)8-4/h1H,6-8H2,2-4H3
InChI keyFWSPXZXVNVQHIF-UHFFFAOYSA-N

安全信息

象形图GHS02
警示用语:Danger
危险声明H225
预防措施声明P210 - P370 + P378 - P403 + P235
危险分类Flam. Liq. 2
储存分类代码3 - Flammable liquids
WGKWGK 3
闪点(F)62.6 °F - closed cup
闪点(C)17 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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