产品介绍:
产品说明
应用
(S)-(-)-Methyl p-tolyl sulfoxide can be used as a nucleophilic reagent to synthesize:
- Optically active β-disulfoxides by reacting with arenesulfinic esters via formation of α-sulfinylcarbanion.
- α-substituted N-hydroxylamines by treating with nitrones via preparation of (S)-(-)-methyl p-tolyl sulfoxide anion.
- 2-O-benzyl-3,4-O-isopropylidene-
L -erythrose by one-carbon homologation of 2,3-O-isopropylidene-L -glyceraldehyde.
包装
1 g in glass bottle
基本信息
线性分子式 | CH3C6H4S(O)CH3 |
分子量 | 154.23 |
Beilstein | 2324696 |
MDL编号 | MFCD00151503 |
PubChem化学物质编号 | 24860755 |
产品性质
质量水平 | 100 |
测定 | 99% |
旋光性 | [α]20/D −145°, c = 2 in acetone |
光学纯度 | ee: 99% (HPLC) |
mp | 75-77 ℃ (lit.) |
SMILES string | Cc1ccc(cc1)S(C)=O |
InChI | 1S/C8H10OS/c1-7-3-5-8(6-4-7)10(2)9/h3-6H,1-2H3/t10-/m0/s1 |
InChI key | FEVALTJSQBFLEU-JTQLQIEISA-N |
安全信息
储存分类代码 | 13 - Non Combustible Solids |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |
个人防护装备 | Eyeshields, Gloves, type N95 (US) |