产品介绍：
产品说明
应用
(1R)-(−)-Camphorquinone can be used as a chiral starting material for the preparation of:
- α-Hydroxycamphors by selective reduction of keto groups using various vegetables.
- Camphor-1,2-diamine platinum(II) complexes for DNA interaction studies.
- Camphoric anhydride by unsensitized photo-oxidation in the presence of oxygen and polar solvents.
- Camphorquinone-based chiral homoallylic amine, which is reacted with aldehydes to produce homoallylic primary amines via imine formation followed by 2-azonia-Cope rearrangement.
包装
5 g in glass bottle
基本信息
| 经验(实验)分子式 | C10H14O2 |
| 分子量 | 166.22 |
| Beilstein | 2327696 |
| MDL编号 | MFCD00082863 |
| PubChem化学物质编号 | 24856697 |
| NACRES | NA.22 |
产品性质
| 质量水平 | 100 |
| 测定 | 99% |
| 旋光性 | [α]20/D −101°, c = 2 in toluene |
| mp | 200-203 ℃ (lit.) |
| SMILES string | CC1(C)[C@@H]2CC[C@@]1(C)C(=O)C2=O |
| InChI | 1S/C10H14O2/c1-9(2)6-4-5-10(9,3)8(12)7(6)11/h6H,4-5H2,1-3H3/t6-,10+/m1/s1 |
| InChI key | VNQXSTWCDUXYEZ-LDWIPMOCSA-N |
安全信息
| 象形图 |   |
| 警示用语： | Danger |
| 危险声明 | H302 - H334 |
| 预防措施声明 | P301 + P312 + P330 |
| 危险分类 | Acute Tox. 4 Oral - Resp. Sens. 1 |
| 储存分类代码 | 11 - Combustible Solids |
| WGK | WGK 3 |
| 闪点(F) | Not applicable |
| 闪点(C) | Not applicable |
| 个人防护装备 | dust mask type N95 (US), Eyeshields, Faceshields, Gloves |
