产品介绍:
产品说明
应用
- Traceless Staudinger ligation reagent with borane protecting group.
- The borane group stabilizes the phosphine against oxidation and can be easily removed with mild basic or acidic conditions to yield the active phosphine.
- After reaction with an azide, the phosphine is eliminated in the presence of water to yield a native amide bond.
- Used in the synthesis of cyclic peptides.
包装
1 g in glass bottle
250 mg in glass bottle
Bottomless glass bottle. Contents are inside inserted fused cone.
法律信息
授权后方可销售,仅供研发使用。美国专利 6,974,884 和相关专利申请
基本信息
经验(实验)分子式 | C15H18BOPS |
分子量 | 288.15 |
PubChem化学物质编号 | 329760266 |
NACRES | NA.22 |
产品性质
测定 | ≥98.0% |
reaction suitability | reaction type: click chemistry reagent type: ligand reaction type: Staudinger Reaction |
mp | 52-55 ℃ |
储存温度 | 2-8℃ |
SMILES string | B.CC(=O)SCP(c1ccccc1)c2ccccc2 |
InChI | 1S/C15H15OPS.BH3/c1-13(16)18-12-17(14-8-4-2-5-9-14)15-10-6-3-7-11-15;/h2-11H,12H2,1H3;1H3 |
InChI key | MXPNVFCCEGQGEN-UHFFFAOYSA-N |
安全信息
象形图 | |
警示用语: | Warning |
危险声明 | H315 - H319 - H335 |
预防措施声明 | P302 + P352 - P305 + P351 + P338 |
危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
靶器官 | Respiratory system |
储存分类代码 | 11 - Combustible Solids |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |
个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |