产品说明
应用
(2R,3S)-(−)-N-Z-6-oxo-2,3-diphenylmorpholine is a Williams chiral auxiliary, which can be used:
- As a template in the preparation of Fmoc-
L -cyclopentylglycine, which acts as an angiotensin II antagonist. - In the synthesis of (
L )-Fmoc-α-Me-Lys(Boc)-OH, a building block for the synthesis of peptidomimetics. - To introduce chirality in the modified amino acid named N-Fmoc 4-(2′-(di-tert-butylmalonyl))-l-phenylalanine.
包装
1 g in glass bottle
250 mg in glass bottle
基本信息
经验(实验)分子式 | C24H21NO4 |
分子量 | 387.43 |
MDL编号 | MFCD00074958 |
PubChem化学物质编号 | 24860004 |
NACRES | NA.22 |
产品性质
测定 | 98% |
旋光性 | [α]25/D −66°, c = 5.5 in methylene chloride |
mp | 205-207 ℃ (lit.) |
储存温度 | 2-8℃ |
SMILES string | O=C1CN([C@H]([C@H](O1)c2ccccc2)c3ccccc3)C(=O)OCc4ccccc4 |
InChI | 1S/C24H21NO4/c26-21-16-25(24(27)28-17-18-10-4-1-5-11-18)22(19-12-6-2-7-13-19)23(29-21)20-14-8-3-9-15-20/h1-15,22-23H,16-17H2/t22-,23+/m0/s1 |
InChI key | HECRUWTZAMPQOS-XZOQPEGZSA-N |
安全信息
象形图 | |
警示用语: | Warning |
危险声明 | H315 - H319 - H335 |
预防措施声明 | P302 + P352 - P305 + P351 + P338 |
危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
靶器官 | Respiratory system |
储存分类代码 | 11 - Combustible Solids |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |
个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |