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O-(Diphenylphosphinyl)hydroxylamine

品牌
Sigma-Aldrich
CAS
72804-96-7
货号
712019
包装型号
规格纯度
≥90% (HPLC)
参考价格
1199.59 *本价格含增值税费
促销
数量
-+
产品介绍:

产品说明

一般描述

O-(Diphenylphosphinyl)hydroxylamine is a general reagent for electrophilic C-amination, which aminates a variety of stable carbanions and Grignard reagents.

应用

O-(Diphenylphosphinyl)hydroxylamine can be used in:

  • The preparation of trans-2-acylaziridines from α, β-unsaturated ketones via amine-catalyzed reaction.
  • Synthesis of enantiomerically pure α, β-diamino acids by stereoselective amination of chiral enolates.
  • The conversion of carbanions into corresponding primary amines.

基本信息

经验(实验)分子式C12H12NO2P
分子量233.20
MDL编号MFCD12755701
PubChem化学物质编号329763105
NACRESNA.22

产品性质

质量水平100
测定≥90% (HPLC)
储存温度2-8℃
SMILES stringNOP(=O)(c1ccccc1)c2ccccc2
InChI1S/C12H12NO2P/c13-15-16(14,11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H,13H2
InChI keySJECIYLGISUNRO-UHFFFAOYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable

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