产品介绍:
产品说明
一般描述
O-(Diphenylphosphinyl)hydroxylamine is a general reagent for electrophilic C-amination, which aminates a variety of stable carbanions and Grignard reagents.
应用
O-(Diphenylphosphinyl)hydroxylamine can be used in:
- The preparation of trans-2-acylaziridines from α, β-unsaturated ketones via amine-catalyzed reaction.
- Synthesis of enantiomerically pure α, β-diamino acids by stereoselective amination of chiral enolates.
- The conversion of carbanions into corresponding primary amines.
基本信息
经验(实验)分子式 | C12H12NO2P |
分子量 | 233.20 |
MDL编号 | MFCD12755701 |
PubChem化学物质编号 | 329763105 |
NACRES | NA.22 |
产品性质
质量水平 | 100 |
测定 | ≥90% (HPLC) |
储存温度 | 2-8℃ |
SMILES string | NOP(=O)(c1ccccc1)c2ccccc2 |
InChI | 1S/C12H12NO2P/c13-15-16(14,11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H,13H2 |
InChI key | SJECIYLGISUNRO-UHFFFAOYSA-N |
安全信息
储存分类代码 | 13 - Non Combustible Solids |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |