产品介绍：
产品说明
一般描述
Barium tert-butoxide is a Brønsted base catalyst that can be used as a precursor of various barium catalysts like barium aryloxide. It can also be used in the preparation of barium diphenylmethanide, applicable in the organometallic chemistry.
应用
Barium tert-butoxide can be used:
- As a catalyst along with various phenolic ligands in the aldol reactions of amides with aldehydes and ketones.
- To prepare yttrium and copper metal complexes by reacting with Y(thd)3 and Cu(thd)2, where “thd” is 2,2,6,6-tetramethylheptane-3,5-dione.
- As an initiator along with an alkyl lithium in the butadiene copolymerization reaction.
- In the iridium catalyzed allylic alkylation of non-stabilized enolates.
包装
1, 10 g in glass bottle
基本信息
| 经验(实验)分子式 | C8H18BaO2 |
| 分子量 | 283.55 |
| MDL编号 | MFCD00082644 |
| PubChem化学物质编号 | 329762972 |
| NACRES | NA.22 |
产品性质
| 质量水平 | 100 |
| 测定 | 85% |
| mp | >200 ℃ |
| 储存温度 | 2-8℃ |
| SMILES string | CC(C)(C)O[Ba]OC(C)(C)C |
| InChI | 1S/2C4H9O.Ba/c2*1-4(2,3)5;/h2*1-3H3;/q2*-1;+2 |
| InChI key | SLPLCLDJTNLWPW-UHFFFAOYSA-N |
安全信息
| 象形图 |    |
| 警示用语： | Danger |
| 危险声明 | H228 - H314 - H335 |
| 预防措施声明 | P210 - P260 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338 |
| 危险分类 | Flam. Sol. 2 - Skin Corr. 1B - STOT SE 3 |
| 靶器官 | Respiratory system |
| 补充剂危害 | EUH014 |
| 储存分类代码 | 4.2 - Pyrophoric and self-heating hazardous materials |
| WGK | WGK 3 |
| 闪点(F) | Not applicable |
| 闪点(C) | Not applicable |
