产品说明
一般描述
(Triphenylsilyl)acetylene is a terminal alkyne. Rhodium-catalyzed asymmetric addition of (triphenylsilyl)acetylene to diphenylphosphinylallene is reported.
应用
(Triphenylsilyl)acetylene may be used in the synthesis of:
- selenothioic acid S-alkyl esters
- methyl 2-(di{ 3, 5-bis[(triphenylsilyl)ethynyl]phenyl}-phosphino)benzoate
- 2-(di{3,5-bis[(triphenylsilyl)ethynyl]phenyl}-phosphino)benzoic acid
包装
5 g in glass bottle
基本信息
线性分子式 | (C6H5)3SiC≡CH |
分子量 | 284.43 |
MDL编号 | MFCD00075453 |
PubChem化学物质编号 | 24862140 |
NACRES | NA.22 |
产品性质
质量水平 | 100 |
测定 | 98% |
mp | 48-50 ℃ (lit.) |
SMILES string | C#C[Si](c1ccccc1)(c2ccccc2)c3ccccc3 |
InChI | 1S/C20H16Si/c1-2-21(18-12-6-3-7-13-18,19-14-8-4-9-15-19)20-16-10-5-11-17-20/h1,3-17H |
InChI key | WADKYPSVXRWORK-UHFFFAOYSA-N |
安全信息
象形图 | |
警示用语: | Warning |
危险声明 | H315 - H319 - H335 |
预防措施声明 | P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338 |
危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
靶器官 | Respiratory system |
储存分类代码 | 11 - Combustible Solids |
WGK | WGK 3 |
闪点(F) | 235.4 °F - closed cup |
闪点(C) | 113 ℃ - closed cup |
个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |