产品介绍：
产品说明
一般描述
(1S)-(+)-Ketopinic acid is a chiral ketone.
应用
用于制备新型手性噁唑烷酮辅助剂和酮基蒎酸衍生聚合物，该聚合物可用于胺的去外消旋化。合成纯手性 2,10-莰烷二醇的原料。用于生成手性席夫碱前体，以制备二乙基 (S)-α-氨基-α-烷基膦酸酯。
(1S)-(+)-Ketopinic acid may be used to prepare:
- Chiral phosphine-oxazoline ligands, which can used in asymmetric palladium-catalyzed Heck reaction of aryl or alkenyl triflates with cyclic alkenes.
- A chiral imino-phosphine ligand, which can be used in palladium-catalyzed asymmetric Diels–Alder reactions to prepare six-membered carbocycles.
- A chiral iminopyridine ligand, which can be used in copper-catalyzed Henry (nitro aldol) reaction between nitromethane and o-anisol to form the corresponding β-hydroxynitroalkane.
包装
1 g in glass bottle
基本信息
| 经验(实验)分子式 | C10H14O3 |
| 分子量 | 182.22 |
| Beilstein | 4180005 |
| MDL编号 | MFCD00168053 |
| PubChem化学物质编号 | 24866367 |
| NACRES | NA.22 |
产品性质
| 测定 | 99% |
| 旋光性 | [α]23/D +58°, c = 1 in chloroform |
| mp | 237-239 ℃ (lit.) |
| SMILES string | CC1(C)C2CCC1(C(O)=O)C(=O)C2 |
| InChI | 1S/C10H14O3/c1-9(2)6-3-4-10(9,8(12)13)7(11)5-6/h6H,3-5H2,1-2H3,(H,12,13)/t6-,10+/m1/s1 |
| InChI key | WDODWBQJVMBHCO-LDWIPMOCSA-N |
安全信息
| 象形图 |  |
| 警示用语： | Warning |
| 危险声明 | H315 - H319 - H335 |
| 预防措施声明 | P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338 |
| 危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 |
| 靶器官 | Respiratory system |
| 储存分类代码 | 11 - Combustible Solids |
| WGK | WGK 3 |
| 个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
