(+)-Dimethyl 2,3-<i>O</i>-isopropylidene-<sc>D</sc>-tartrate

产品介绍：

产品说明

一般描述

(+)-Dimethyl 2,3-O-isopropylidene-D-tartrate is a chiral reagent used in organic synthesis. It is prepared by the reaction-rectification process from D -tartrate, and 2,2-dimethoxypropane.{138]

应用

TADDOL 手性助剂、联吡啶配体和苏糖醇的有用结构单元。
(+)-Dimethyl 2,3-O-isopropylidene-D-tartrate can be used as a starting material for the synthesis of:

Deuterated 1-deoxy-D-xylose.
C-terminal peptide -oxo-aldehydes using Fmoc solid-phase peptide synthesis methodology (SPPS).
Bis-Weinreb amide, a key intermediate for the preparation of myo-inositol analog via ring-closing metathesis.

包装

5 g in glass bottle

基本信息

经验(实验)分子式	C₉H₁₄O₆
分子量	218.20
Beilstein	3548490
MDL编号	MFCD00040504
PubChem化学物质编号	24863661
NACRES	NA.22

产品性质

质量水平	100
测定	98%
旋光性	[α]20/D +54°, neat
折射率	n20/D 1.439 (lit.)
bp	80-82 ℃/0.1 mmHg (lit.)
密度	1.19 g/mL at 25 ℃ (lit.)
SMILES string	COC(=O)[C@H]1OC(C)(C)O[C@@H]1C(=O)OC
InChI	1S/C9H14O6/c1-9(2)14-5(7(10)12-3)6(15-9)8(11)13-4/h5-6H,1-4H3/t5-,6-/m0/s1
InChI key	ROZOUYVVWUTPNG-WDSKDSINSA-N

安全信息

储存分类代码	10 - Combustible liquids
WGK	WGK 3
闪点(F)	closed cup
闪点(C)	closed cup
个人防护装备	Eyeshields, Gloves

(+)-Dimethyl 2,3-O-isopropylidene-D-tartrate

(+)-二甲基 2,3-O-异亚丙基-D-酒石酸酯