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Ethyl Acetoacetate

乙酰乙酸乙酯

品牌
Sigma-Aldrich
CAS
141-97-9
货号
W241512
规格纯度
natural, ≥97%, FG
参考价格
433.21 *本价格含增值税费
促销
数量
-+
产品介绍:

产品说明

一般描述

Ethyl acetoacetate is a bidentate chelating agent. It reacts with tetraalkoxy titanium to afford stable titanic esters. Its reaction with various alkylating reagents has been studied.
Ethyl acetoacetate is ethyl ester of acetoacetic acid. Ethyl acetoacetate exhibits keto-enol tautomerism. Ethyl acetoacetate reacts with aromatic amines in the presence of commercially available zeolite HSZ-360 to form symmetric diphenylureas.

应用

Ethyl acetoacetate was used to investigate the catalytic activity of lipase B from Candida antarctica (CAL-B) during decarboxylative aldol addition and Knoevenagel reaction between 4-nitrobenzaldehyde (4-NBA) and ethyl acetoacetate. Ethyl acetoacetate has been used in quantitative determination of urinary δ-aminolevulinic acid by condensation reaction.

包装

100 g in glass bottle
1 kg in glass bottle
5 kg in poly drum

基本信息

线性分子式CH3COCH2COOC2H5
分子量130.14
FEMA编号2415
Beilstein385838
EC 号205-516-1
欧洲委员会编号240c
MDL编号MFCD00009199
PubChem化学物质编号24901056
Flavis编号9.402
NACRESNA.21

产品性质

质量水平400
等级FG
Halal
Kosher
natural
agencyfollows IFRA guidelines
reg. complianceEU Regulation 1223/2009
EU Regulation 1334/2008 & 178/2002
FDA 21 CFR 117
蒸汽密度4.48 (vs air)
蒸汽压1 mmHg ( 28.5 ℃)
测定≥97%
自燃温度580 °F
expl. lim.9.5 %
折射率n20/D 1.418-1.421
bp181 ℃ (lit.)
mp−43 ℃ (lit.)
溶解性water: soluble 35 part
organic solvents: soluble
密度1.029 g/mL at 20 ℃ (lit.)
文件see Safety & Documentation for available documents
性状检查apple; fatty; green; fruity
application(s)flavors and fragrances
食品过敏原no known allergens
致敏芳香化合物no known allergens
SMILES stringCCOC(=O)CC(C)=O
InChI1S/C6H10O3/c1-3-9-6(8)4-5(2)7/h3-4H2,1-2H3
InChI keyXYIBRDXRRQCHLP-UHFFFAOYSA-N

安全信息

储存分类代码10 - Combustible liquids
WGKWGK 1
闪点(F)164.3 °F - closed cup
闪点(C)73.5 ℃ - closed cup
个人防护装备Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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