产品说明
一般描述
2-Chloromethyl-2,3-dihydrothieno[3,4-b]-1,4-dioxine (EDOT-Cl) can be prepared by reacting 3,4-dimethoxythiophene with 3-chloro-1,2-propanediol via transesterification. The six-memebered ring of the molecule exhibits twisted conformation. It acts as an intermediate during the multi-step synthesis of poly(sulfobetaine-3,4-ethylenedioxythiophene) (PSBEDOT), a conjugated polymer.
应用
2-Chloromethyl EDOT is a key building block for the incorporation of EDOT (3,4-ethylenedioxythio-phene) into copolymers.
It may be used in the synthesis of the following EDOT derivatives:
- 2-[((6-hexyloxy-9,10-anthraquinone)-2-yl)oxymethyl]-2,3-dihydrothieno[3,4-b][1,4]dioxine (AQ-EDOT)
- 2-[(N′-(10-nonadecyl)perylene-3,4,9,10-biscarboximide-N-yl)4-phenoxymethyl]-2,3-dihydrothieno[3,4-b][1,4]dioxine (PTCDI-EDOT)
- 2-[((6-hexyloxy-11,11,12,12-tetracyanoanthraquinodimethane)-2-yl)-oxymethyl]-2,3-dihydrothieno[3,4-b][1,4]dioxine (TCAQ-EDOT)
包装
1 g in glass bottle
其他说明
EDOT-Based Copolymers with Pendant Anthraquinone Units: Analysis of Their Optoelectronic Properties within the Double-Cable Context
基本信息
经验(实验)分子式 | C7H7ClO2S |
分子量 | 190.65 |
MDL编号 | MFCD17014651 |
PubChem化学物质编号 | 329768732 |
NACRES | NA.22 |
产品性质
质量水平 | 100 |
测定 | 95% |
形式 | solid |
mp | 39-44 ℃ |
转变温度 | flash point >230 °F |
SMILES string | ClCC1COc2cscc2O1 |
InChI | 1S/C7H7ClO2S/c8-1-5-2-9-6-3-11-4-7(6)10-5/h3-5H,1-2H2 |
InChI key | UOXHKOVMJCKBOG-UHFFFAOYSA-N |
安全信息
象形图 | |
警示用语: | Warning |
危险声明 | H302 |
预防措施声明 | P301 + P312 + P330 |
危险分类 | Acute Tox. 4 Oral |
储存分类代码 | 13 - Non Combustible Solids |
WGK | WGK 3 |
闪点(F) | Not applicable |
闪点(C) | Not applicable |