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2-Chloromethyl-2,3-dihydrothieno[3,4-b]-1,4-dioxine

品牌
Sigma-Aldrich
CAS
857419-46-6
货号
802247
包装型号
规格纯度
95%
参考价格
1340.46 *本价格含增值税费
促销
数量
-+
产品介绍:

产品说明

一般描述

2-Chloromethyl-2,3-dihydrothieno[3,4-b]-1,4-dioxine (EDOT-Cl) can be prepared by reacting 3,4-dimethoxythiophene with 3-chloro-1,2-propanediol via transesterification. The six-memebered ring of the molecule exhibits twisted conformation. It acts as an intermediate during the multi-step synthesis of poly(sulfobetaine-3,4-ethylenedioxythiophene) (PSBEDOT), a conjugated polymer.

应用

2-Chloromethyl EDOT is a key building block for the incorporation of EDOT (3,4-ethylenedioxythio-phene) into copolymers.
It may be used in the synthesis of the following EDOT derivatives:

  • 2-[((6-hexyloxy-9,10-anthraquinone)-2-yl)oxymethyl]-2,3-dihydrothieno[3,4-b][1,4]dioxine (AQ-EDOT)
  • 2-[(N′-(10-nonadecyl)perylene-3,4,9,10-biscarboximide-N-yl)4-phenoxymethyl]-2,3-dihydrothieno[3,4-b][1,4]dioxine (PTCDI-EDOT)
  • 2-[((6-hexyloxy-11,11,12,12-tetracyanoanthraquinodimethane)-2-yl)-oxymethyl]-2,3-dihydrothieno[3,4-b][1,4]dioxine (TCAQ-EDOT)

包装

1 g in glass bottle

其他说明

EDOT-Based Copolymers with Pendant Anthraquinone Units: Analysis of Their Optoelectronic Properties within the Double-Cable Context

基本信息

经验(实验)分子式C7H7ClO2S
分子量190.65
MDL编号MFCD17014651
PubChem化学物质编号329768732
NACRESNA.22

产品性质

质量水平100
测定95%
形式solid
mp39-44 ℃
转变温度flash point >230 °F
SMILES stringClCC1COc2cscc2O1
InChI1S/C7H7ClO2S/c8-1-5-2-9-6-3-11-4-7(6)10-5/h3-5H,1-2H2
InChI keyUOXHKOVMJCKBOG-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302
预防措施声明P301 + P312 + P330
危险分类Acute Tox. 4 Oral
储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable

Sigma-Aldrich

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