产品介绍：
产品说明
一般描述
(2-Naphthylmethyl)zinc bromide is an organozinc halide, which is typically used as a reagent in Negishi cross-coupling reactions. In this process, the organozinc halide reacts with organic halides or triflates to form a carbon-carbon bond in the presence of a Pd catalyst.
应用
(2-Naphthylmethyl)zinc bromide can be used as a reagent for the synthesis of:
- 4-(5,6-dimethoxy-2-(naphthalen-2-ylmethyl)pyridin-3-yl)benzonitrile from 4-(2-bromo-5,6-dimethoxypyridin-3-yl)benzonitrile using Pd catalyst.
- (E)-stilbene, (2,2′-[1,4-phenylenedi-(1E)-2,1-ethenediyl]bis[naphthalene]) from 1,4-benzenedicarboxaldehyde in the presence of Pd catalyst and a silylating agent.
包装
50 mL in Sure/Seal™
法律信息
Rieke® Metals, Inc. 产品 ®Rieke Metals, Inc. 的注册商标
基本信息
| 线性分子式 | C10H7CH2ZnBr |
| 分子量 | 286.48 |
| MDL编号 | MFCD01311438 |
| PubChem化学物质编号 | 24873248 |
| NACRES | NA.22 |
产品性质
| 质量水平 | 100 |
| 浓度 | 0.5 M in THF |
| 密度 | 0.978 g/mL at 25 ℃ |
| 储存温度 | 2-8℃ |
| SMILES string | Br[Zn]Cc1ccc2ccccc2c1 |
| InChI | 1S/C11H9.BrH.Zn/c1-9-6-7-10-4-2-3-5-11(10)8-9;;/h2-8H,1H2;1H;/q;;+1/p-1 |
| InChI key | IKDINBHMSAHXCA-UHFFFAOYSA-M |
安全信息
| 象形图 |    |
| 警示用语： | Danger |
| 危险声明 | H225 - H319 - H335 - H336 - H351 |
| 预防措施声明 | P202 - P210 - P233 - P240 - P305 + P351 + P338 - P308 + P313 |
| 危险分类 | Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 |
| 补充剂危害 | EUH014 - EUH019 |
| 储存分类代码 | 4.3 - Hazardous materials, which set free flammable gases upon contact with water |
| WGK | WGK 3 |
| 闪点(F) | 1.4 °F - closed cup |
| 闪点(C) | -17 ℃ - closed cup |
