应用
α,α,α',α'-Tetrabromo-o-xylene reacts with 5endo,6endo-bis-chlormethyl-norborn-2-en to obtain trans/cis-2,3-bis(chloromethyl)-1,4-methano-1,2,3,4-tetrahydroanthracene. Further, it is involved in the preparation of 1-(3-butenyl)-2-(deuteriomethyl)benzene by reacting with allylmagnesium bromide. In addition this, it is used to prepare exo-benzocyclobuteno-1,2,3,4-tetrahydro-1,4-methanoanthracene by reacting with exo-1,4,4a,8b-tetrahydro-1,4-methanobiphenylene.
备注
Incompatible with strong oxidizing agents and strong bases.
基本信息
MDL
MFCD00000131
EINECS
236-176-2
分子式
C8H6Br4
分子量
421.75
熔点
114-118°
灵敏度
Ambient temperatures.
形态
Crystalline powder
溶解性
Insoluble in water.
Beilstein
2211698
GHS危害和防范说明
GHS符号
Hazard Statements
H314-H318-H317-H335
Causes severe skin burns and eye damage.Causes serious eye damage.May cause an allergic skin reaction.May cause respiratory irritation.
Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.
安全信息
UN#
UN3261
危险等级
8
包装组
II
危险类别
34-37-43
Causes burns.Irritating to respiratory system.May cause sensitization by skin contact.
安全等级
26-36/37/39-45-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste
欧盟危险品标志
TSCA
是