应用
Sodium triacetoxyborohydride is used as a reagent in reductive amination of ketones, aldehydes and lactamization of carbonyl compounds with amines. It also serves as a reducing agent in organic synthesis.
备注
Moisture sensitive. Incompatible with strong oxidizing agents, water, alcohols and acids.
基本信息
MDL
MFCD00012211
EINECS
000-000-0
分子式
Na(CH3CO2)3BH
分子量
211.94
熔点
ca 110° dec.
灵敏度
Moisture Sensitive. Ambient temperatures.
形态
Powder
溶解性
Soluble in dimethyl sulfoxide, methanol, benzene, toluene, terahydrofuran, dioxane and methylene chloride.
Beilstein
4047608
GHS危害和防范说明
GHS符号
Hazard Statements
H228-H261-H315-H318-H335
Flammable solid.In contact with water releases flammable gas.Causes skin irritation.Causes serious eye damage.May cause respiratory irritation.
Precautionary Statements
P223-P210-P231+P232-P305+P351+P338-P405-P501a
Keep away from any possible contact with water, because of violent reaction and possible flash fire.Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Handle under inert gas. Protect from moisture.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.
安全信息
危险等级
4.3
包装组
II
危险类别
11-15-37/38-41
Highly flammable.Contact with water liberates extremely flammable gases.Irritating to respiratory system and skin.Risk of serious damage to eyes.
安全等级
7/8-26-33-37/39-43-60
Keep container tightly closed and dry.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Take precautionary measures against static discharges.Wear suitable gloves and eye/face protection.In case of fire, use ... (indicate in the space the precise type of fire fighting equipment. If water increases risk, odd 'Never use water')This material and its container must be disposed of as hazardous waste
欧盟危险品标志
TSCA
是