应用
Oxidation.Ruthenium(III) chloride hydrate is used as a catalyst for alkyne functionalization and oxidation reactions. It is used as key raw materials for the preparation of various ruthenium-based catalysts, including Grubbs?’ catalysts. It is utilized in the preparation of nanoparticulate ruthenium-aluminum oxyhydroxide catalyst, which is efficient for dehydrogenation of alcohols to the corresponding aldehydes. It is also involved in the synthesis of 2-ethyl-3-methylquinolines from primary aromatic amines and triallylamine.

备注
Hygroscopic. Incompatible with zinc.

基本信息

MDL
MFCD00149844

EINECS
233-167-5

分子式
Cl₃Ru?xH₂O

分子量
207.43(anhy)

熔点
100°dec

灵敏度
Hygroscopic. Ambient temperatures.

形态
Crystalline Soluble

溶解性
Very soluble in water. Soluble in alcohol, acetone.

Merck
14,8302

GHS危害和防范说明

GHS符号

Hazard Statements
H290-H302-H314-H318-H412
May be corrosive to metals.Harmful if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.Harmful to aquatic life with long lasting effects.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
22-34-53
Harmful if swallowed.Causes burns.May cause long-term adverse effects in the aquatic environment.

安全等级
20-26-36/37/39-45-60-61
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous wasteAvoid release to the environment. Refer to special instructions/safety data sheets.

欧盟危险品标志

RTECS
VM2650000

TSCA
是