应用
Rhodium(III) chloride hydrate is used as a catalyst for the conversion of methane to acetic acid, isomerization of alkenes, reduction of aromatic rings and hydration of acetylene. It is involved in the hydrosilylation of alfa,beta-unsaturated esters to form dimethylketene trimethylsilyl acetals. It plays an important role as a catalyst for conjugate reduction of cinnamaldehydes followed by cross-coupling with arylboronic acids.

备注
Hygroscopic. Incompatible withoxidizing agents.

基本信息

MDL
MFCD00149839

EINECS
233-165-4

分子式
RhCl₃•xH₂O

分子量
209.26(anhy)

熔点
100° dec.

灵敏度
Hygroscopic. Store under Nitrogen. Ambient temperatures.

形态
Crystalline

溶解性
Soluble in water and alcohol. Slightly soluble in acetone.

Merck
14,8188

GHS危害和防范说明

GHS符号

Hazard Statements
H290-H302-H318-H341
May be corrosive to metals.Harmful if swallowed.Causes serious eye damage.Suspected of causing genetic defects.

Precautionary Statements
P201-P280-P305+P351+P338-P310a-P405-P501a
Obtain special instructions before use.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
III

危险类别
22-41-68
Harmful if swallowed.Risk of serious damage to eyes.Possible risk of irreversible effects.

安全等级
26-36/37/39-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA
是