应用
It is employed as a catalyst for the carboxylation of styrene oxide and as a reactant involved in epoxidation of arylalkenes, boration of allylic epoxides, Wittig reactions, selective dimerization of α-olefins, and synthesis of indoles. It has also been shown to be part of Phosphonium salts, having antiviral activity against influenza virus A.
备注
Hygroscopic. Store away from oxidizing agents, humidity and water/moisture. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas.
基本信息
MDL
MFCD00011843
EINECS
228-330-2
分子式
CH3(CH2)2P(C6H5)3Br
分子量
385.29
熔点
236-240°
灵敏度
Hygroscopic. Ambient temperatures.
形态
Powder
溶解性
Soluble in water.
Beilstein
3599726
GHS危害和防范说明
GHS符号
Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.
Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.
安全信息
危险类别
36/37/38
Irritating to eyes, respiratory system and skin.
安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
TSCA
否