应用
Employed in the synthesis of enones by selenenylation of α-cyano ketones with lithium naphthalenide. Phenylselenyl bromide was used in the preparation of exo-2-methyl-7-phenylselenyl-octahydro-8-oxa-2,7b-diaza-dicyclopenta[a,e]pentalene-1,3-dione and endo-2-methyl-7-phenylselanyl-octahydro-8-oxa-2,7b-diaza-dicyclopenta[a,e]pentalene-1,3-dione.
备注
Moisture Sensitive. Store away from air and water/moisture. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.
基本信息
MDL
MFCD00000047
EINECS
252-238-1
分子式
C6H5BrSe
分子量
235.98
熔点
56-62°
沸点
107-108°/15mm
灵敏度
Moisture Sensitive. Ambient temperatures.
形态
Crystals
溶解性
Soluble in toluene, very faint turbidity.
Beilstein
2039772
GHS危害和防范说明
GHS符号
Hazard Statements
H301-H331-H373-H400-H410
Toxic if swallowed.Toxic if inhaled.May cause damage to organs through prolonged or repeated exposure.Very toxic to aquatic life.Very toxic to aquatic life with long lasting effects.
Precautionary Statements
P260-P301+P310a-P304+P340-P311a-P405-P501a
Do not breathe dust/fume/gas/mist/vapours/spray.Do not breathe dust/fume/gas/mist/vapours/spray.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.
安全信息
UN#
UN2928
危险等级
6.1
包装组
II
危险类别
23/25-33-50/53
Toxic by inhalation and if swallowed.Danger of cumulative effects.Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
安全等级
20/21-28-45-60-61
When using do not eat, drink or smoke.After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer).In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous wasteAvoid release to the environment. Refer to special instructions/safety data sheets.
欧盟危险品标志
TSCA
否
