应用
Selective hydrogenationPalladium (5%) on calcium carbonate powder (reduced) is a heterogeneous and a mild catalyst, used in the hydrogenation of aromatic and aliphatic nitro groups, reductive alkylation/amination, hydrogenation of aromatic carbonyls, olefins, and nitriles. It has high selectivity towards certain chemical reactants, and is often the preferred heterogeneous catalyst for a wide variety of chemical reactions. Partially deactivated form of palladiuim (5%) on calcium carbonate is known as Lindlar catalyst, which is useful for chemo and stereoselective hydrogenations, such as alkynes to cis-alkenes (for e.g., Vitamin synthesis).
备注
Incompatible with materials like strong oxidizing agents and arsenic.
基本信息
MDL
MFCD03427452
灵敏度
Ambient temperatures.
形态
Powder
溶解性
Insoluble in most organic solvents.
GHS危害和防范说明
GHS符号
Hazard Statements
H333-H360-H401-H411
May be harmful if inhaled.May damage fertility or the unborn child.Toxic to aquatic life.Toxic to aquatic life with long lasting effects.
Precautionary Statements
P201-P280-P202-P308+P313-P405-P501a
Obtain special instructions before use.Wear protective gloves/protective clothing/eye protection/face protection.Do not handle until all safety precautions have been read and understood.IF exposed or concerned: Get medical advice/attention.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.
安全信息
UN#
UN3077
危险等级
9
包装组
III
危险类别
61-33-62-51/53
May cause harm to the unborn child.Danger of cumulative effects.Possible risk of impaired fertility.Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
安全等级
53-36/37-45-57-60
Avoid exposure - obtain special instructions before use.Wear suitable protective clothing and gloves.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Use appropriate container to avoid environmental contamination.This material and its container must be disposed of as hazardous waste
欧盟危险品标志
TSCA
是
